2-2. Scatter plot for calculated vs. experimental nonionic CMC for 77 surfactants, using three descriptors
2-3. Structures of the surfactants included in the anionic CMC correlations
2-4. Scatter plot for calculated vs. experimental anionic CMC for 119 surfactants, using three descriptors
2-5. Normalized CMC vs. temperature for a) sulfates and b) sulfonates
2-6. Structures of the surfactants included in the nonionic cloud point correlations
2-7. Scatter plot for calculated vs. experimental nonionic cloud point for 62 surfactants, using three descriptors
2-8. Topological descriptor values vs. carbon number for the different hydrophobic structures in the cloud point correlation
2-9. Structures of the surfactants included in the Krafft point correlations
2-10. Scatter plot for calculated vs. experimental Krafft point for 44 surfactants, using four descriptors
2-11. Scatter plot for the four descriptor regression of calculated to experimental molar volume of 78 diverse alkanes and alkenes
2-12. Scatter plot for the one descriptor (0c) regression of calculated to experimental molar volume of 78 diverse alkanes and alkenes, showing structures with greatest steric influence on the molecular volume
3-1. W/O solubilization, binary mixtures of
Spans with Tween 85
3-2. W/O solubilization, binary mixtures of Spans with Tween 80
3-3. W/O solubilization, binary mixtures of Spans with Tween 20
3-4. W/O solubilization, binary mixtures of Spans with Tween 21
3-5. W/O solubilization, binary mixtures of Spans with Tween 81
3-6. Solubilization assuming hydration, binary mixtures of Spans with Tween 85
3-7. W/O solubilization in ternary Span/Tween mixtures
3-8. W/O solubilization, weight % excursion for Tween 81
3-9. W/O solubilization, weight % excursion for Span 80/Tween 85 mixtures
3-10. W/S ratio vs. S/O ratio, for Span 80/Tween 85 NHLB=10 mixture
3-11. W/O solubilization in C10-C16 n-alkane/Tween 81 microemulsions
3-12. W/O solubilization in C8-C16 n-alkane/Span 80/Tween 85 microemulsions
3-13. W/O solubilization in C8-C16 n-Alkane/Span 20/Tween 85 microemulsions
3-14. W/O solubilization in C8, C12, C16 n-alkane/Span 20/Tween 85 microemulsions
3-15. Curvature model for the solubilization behavior of Span/Tween W/O microemulsions
3-16. W/O solubilization, binary mixtures with Igepal CO series surfactants in cyclohexane
3-17. Solubilization of electrolyte solutions in Igepal/cyclohexane W/O microemulsions
3-18. W/O solubilization in hexadecane/Span/ethoxylated Castor oil microemulsions
4-1. Effect of micellar lifetime (slow relaxation time) on technological processes
4-2. Variation of the slow relaxation time (t2) of 100 mM SDS as a function of alcohol concentration
4-3. Slow relaxation time for mixtures of SDS and higher alcohols. The concentration of the mixtures remains constant at 100 mM (SDS+alcohol)
4-4. Viscosity of glycerol/water mixtures
4-5. Conductivity of glycerol/water/SDS mixtures
4-6. Slow relaxation time of 100 mM SDS with different glycerol/water ratios
4-7. Slow relaxation time of SDS at a 1:1 glycerol/water ratio
4-8. Slow relaxation time (t2) vs. size of counterion, for 3 and 30 mM concentrations of tetraalkyl-ammonium chloride salts, where the alkyl group varies from methyl to pentyl
4-9. Slow relaxation time vs. concentration, for tetraethylammonium chloride in 150 mM SDS
4-10. Slow relaxation time vs. concentration, for tetraethylammonium chloride in 75 mM SDS
4-11. Slow relaxation time of mixed anionic and nonionic surfactants, for different mixtures of 100 mM combined SDS + Tween 80
4-12. Typical electrical conductivity vs. time traces for pressure-jump experiments. These examples show the decrease in signal as the proportion of nonionic surfactant increases
4-13. Slow relaxation time (t2) for mixed anionic and nonionic surfactants, for different mixtures of 0.5 wt% combined AOT + Arlacel 20
4-14. Slow relaxation time vs. additive concentration for 100 mM SDS with the additives glycerol, glycine and sodium octanoate
4-15. Slow relaxation time vs. concentration for mixed sodium octanoate/SDS micelles, compared with pure SDS micelles
4-16. Surface tension vs. concentration for sodium octanoate
4-17. Apparent dynamic surface tension of glycerol
4-18. Equilibrium surface tension of methanol/water mixtures
4-19. 23Na chemical shift (d ) vs. SDS concentration for the entire range from 2 to 400 mM
4-20. Spin-lattice relaxation time (T1) vs. SDS concentration for the entire range from 2 to 400 mM
4-21. 23Na chemical shift (d ) vs. the inverse of the SDS concentration for the entire range from 2 to 400 mM
4-22. Spin-lattice relaxation time (T1) vs. the inverse of the SDS concentration for the entire range from 2 to 400 mM, showing linear relationship of T1 to 1/[SDS] over certain concentration ranges
4-23. Surface tension vs. concentration for CPC, establishing a CMC of 0.9 mM
4-24. Electrical conductivity vs. concentration for MTAB
4-25. Slow relaxation time (t2) vs. concentration for CPC
4-26. Slow relaxation time vs. concentration for MTAB
4-27. Slow relaxation time vs. concentration for CTAB
4-28. Slow relaxation time conductivity signal amplitude vs. concentration for CPC
4-29. Fabric wetting time vs. concentration for MTAB
4-30. Fabric wetting time vs. concentration for CTAB
4-31. Foam height vs. concentration for MTAB
4-32. Foamability vs. concentration for MTAB
4-33. Nonionic surfactant micellar kinetics via temperature-jump
4-34. Measuring light scattering with absorbance spectroscopy
4-35. Absorbance spectrum of Arlasolve 200
4-36. Log absorbance vs. log wavelength for Brij 78
4-37. Absorbance spectrum of SDS
4-38. Ultraviolet absorbance spectrum of water vs. temperature
4-39. Absorbance spectrum of Igepal CO-720
4-40. Absorbance spectrum of Brij 97