SOLUBLE
AND FOAMING BATH OILS
SOLUBLE BATH OILS
Composition
and Function:
Soluble bath oils are
either anhydrous concentrates consisting of
perfume and surfactant or solubilized products
consisting of perfume, surfactant, and water.
They are formulated as sparkling, clear products.
When added to bath water, they form clear
dispersions.
Soluble bath oils may
contain between 5% to 20% perfume oil.
Solubilization of the perfume oil can usually be
accomplished easily and economically by means of
a hydrophilic surfactant.
Formulation:
TWEEN(r) and BRIJ(r)
surfactants in the HLB range of 12 to 18 are
widely used in perfume oil solubilization.
ARLASOLVE(r) 200 Liquid/Gel Isoceteth-20 and
G-2162 PEG-25 propylene glycol stearate are
excellent solubilizers in these formulations. Two
to five parts of surfactant will solubilize one
part of many perfume oils in water. Formula B-3
exemplifies the use of our surfactant in this
type product. By building from this basic
formula, and endless variety of soluble bath oils
can be formulated.
| Formula
B-3 |
| |
|
SOLUBLE
BATH OIL |
|
%,
Weight |
| A |
|
Perfume |
|
5.0 |
| |
|
TWEEN 20
Polysorbate or ARLASOLVE 200
Liquid/Gel
|
|
20.0 5.0-25.0
|
| |
|
Preservative |
|
q.s. |
| B |
|
Water |
|
q.s.-100.0 |
| |
|
|
|
100.0 |
Preparation:
Mix (A)
well. Add (B) slowly to (A) with agitation.
Filter if necessary.
FOAMING BATH OILS
Composition
and Function:
Foaming bath oils
(sometimes referred to as bubble baths) provide
both fragrance and foaming action. In addition to
being luxury bath items, these products serve the
additional esthetic function of eliminating or
reducing the soap film that produces bathtub
ring.
Foaming bath oils are
similar to the traditional soluble bath oils with
foam builders are: alkyl aryl sulfonates; sodium,
potassium, ammonium and alkanolamine lauryl
sulfates; and sodium, ammonium and alkanolamine
ether sulfates. As foam stabilizers,
alkanolamides of coconut fatty acid or of lauric
acid are commonly used.
Thickeners and
sequestrants are sometimes added as minor
adjuncts. When additional viscosity is desired,
carboxymethyl cellulose, methyl cellulose, and
other gums are commonly added. The alkanolamines,
when used as foam stabilizers, will also raise
viscosity.
Foaming detergent bath
products require warning labels. The caution
statement required by 21 CFR Part 740.17 is;
"Caution--Use only as directed. Extensive
use or prolonged exposure may cause irritation to
skin and urinary tract. Discontinue use if rash,
redness or itching occurs. Consult your physician
if irritation persists. Keep out of reach of
children".
Nonionic ethoxylates of
alcohols have not been known for their foaming
ability, but ARLASOLVE 200 Liquid/Gel
Isoceteth-20 has excellent foaming ability which
makes it a logical candidate for shampoos,
shaving creams and bubble baths.
The Ross-Miles test for
measuring foam, which uses a very dilute solution
of surfactant in water indicates the superiority
of ARLASOLVE 200 Liquid/Gel as a foamer. This
test does not measure foam quality or density,
just the height of the head of foam.
| ROSS-MILES
FOAM TEST, .05% SOLIDS
CONCENTRATIONS AT 25°C
|
| Surfactant |
|
Initial Height
|
|
Height
after 5 Minutes
|
| Sodium Lauryl
Sulfate |
|
247mm |
|
237mm |
| ARLASOLVE 200
Liquid/Gel |
|
210mm |
|
200mm |
| TWEEN 20 |
|
117mm |
|
112mm |
Formulation:
In some cases, an
emollient such as ARLAMOL(r) E PPG-15 Stearyl
Ether can be included in a foaming bath oil
formula. Formula B-4 is a clear, viscous liquid
which, when added to the bath, readily disperses
and still produces a significant amount of foam.
| Formula
B-4 |
| FOAMING
EMOLLIENT BATH OIL |
|
%,
Weight |
| ARLAMOL E |
|
10.0 |
| ARLATONE T
PEG-40 Sorbitan
Peroleate
|
|
10.0 |
| Triethanolamine
lauryl sulfate, 40% solution
|
|
25.0 |
| Amido-either
sulfate |
|
45.0 |
| Water |
|
45.0 |
| |
|
100.0
|
Preparation:
Mix all
ingredients together with moderate heat and
agitation.
Formula B-5 illustrates
the use of ARLASOLVE 200 Liquid/Gel to solubilize
the fragrance in a foaming bath oil. The ratio of
surfactant to perfume is dependent on the type of
fragrance which is used.
| Formula
B-5 |
| |
|
BUBBLE
BATH & BATH OIL |
|
%,
Weight |
| A |
|
Fragrance |
|
4.4 |
| |
|
ARLASOLVE 200
Liquid/Gel |
|
q.s. |
| |
|
Sodium lauryl
sulfoacetate 70% active |
|
10.0 |
| B |
|
Water |
|
q.s.
to 98.8 |
| C |
|
Lauramide DEA |
|
1.0 |
| |
|
Preservative |
|
0.2 |
| |
|
|
|
100.0 |
Preparation:
Add (B) to
(A) with good agitation. Add (C) with stirring,
with slight heating to facilitate solution when
necessary. Adjust the final product to a pH of
less than 7.0 with an acid such as citric. Filter
if necessary.
|