SOLUBLE AND FOAMING BATH OILS

SOLUBLE BATH OILS

Composition and Function:

Soluble bath oils are either anhydrous concentrates consisting of perfume and surfactant or solubilized products consisting of perfume, surfactant, and water. They are formulated as sparkling, clear products. When added to bath water, they form clear dispersions.

Soluble bath oils may contain between 5% to 20% perfume oil. Solubilization of the perfume oil can usually be accomplished easily and economically by means of a hydrophilic surfactant.

Formulation:

TWEEN(r) and BRIJ(r) surfactants in the HLB range of 12 to 18 are widely used in perfume oil solubilization. ARLASOLVE(r) 200 Liquid/Gel Isoceteth-20 and G-2162 PEG-25 propylene glycol stearate are excellent solubilizers in these formulations. Two to five parts of surfactant will solubilize one part of many perfume oils in water. Formula B-3 exemplifies the use of our surfactant in this type product. By building from this basic formula, and endless variety of soluble bath oils can be formulated.

Formula B-3
    SOLUBLE BATH OIL   %, Weight
A   Perfume   5.0
    TWEEN 20 Polysorbate

or ARLASOLVE 200 Liquid/Gel

  20.0

5.0-25.0

    Preservative   q.s.
B   Water   q.s.-100.0
        100.0

Preparation:

Mix (A) well. Add (B) slowly to (A) with agitation. Filter if necessary.

 

FOAMING BATH OILS

Composition and Function:

Foaming bath oils (sometimes referred to as bubble baths) provide both fragrance and foaming action. In addition to being luxury bath items, these products serve the additional esthetic function of eliminating or reducing the soap film that produces bathtub ring.

Foaming bath oils are similar to the traditional soluble bath oils with foam builders are: alkyl aryl sulfonates; sodium, potassium, ammonium and alkanolamine lauryl sulfates; and sodium, ammonium and alkanolamine ether sulfates. As foam stabilizers, alkanolamides of coconut fatty acid or of lauric acid are commonly used.

Thickeners and sequestrants are sometimes added as minor adjuncts. When additional viscosity is desired, carboxymethyl cellulose, methyl cellulose, and other gums are commonly added. The alkanolamines, when used as foam stabilizers, will also raise viscosity.

Foaming detergent bath products require warning labels. The caution statement required by 21 CFR Part 740.17 is; "Caution--Use only as directed. Extensive use or prolonged exposure may cause irritation to skin and urinary tract. Discontinue use if rash, redness or itching occurs. Consult your physician if irritation persists. Keep out of reach of children".

Nonionic ethoxylates of alcohols have not been known for their foaming ability, but ARLASOLVE 200 Liquid/Gel Isoceteth-20 has excellent foaming ability which makes it a logical candidate for shampoos, shaving creams and bubble baths.

The Ross-Miles test for measuring foam, which uses a very dilute solution of surfactant in water indicates the superiority of ARLASOLVE 200 Liquid/Gel as a foamer. This test does not measure foam quality or density, just the height of the head of foam.

ROSS-MILES FOAM TEST,

.05% SOLIDS CONCENTRATIONS AT 25°C

Surfactant   Initial

Height

  Height after

5 Minutes

Sodium Lauryl Sulfate   247mm   237mm
ARLASOLVE 200 Liquid/Gel   210mm   200mm
TWEEN 20   117mm   112mm

Formulation:

In some cases, an emollient such as ARLAMOL(r) E PPG-15 Stearyl Ether can be included in a foaming bath oil formula. Formula B-4 is a clear, viscous liquid which, when added to the bath, readily disperses and still produces a significant amount of foam.

Formula B-4
FOAMING EMOLLIENT BATH OIL   %, Weight
ARLAMOL E   10.0
ARLATONE T PEG-40

Sorbitan Peroleate

  10.0
Triethanolamine lauryl sulfate,

40% solution

  25.0
Amido-either sulfate   45.0
Water   45.0
    100.0

Preparation:

Mix all ingredients together with moderate heat and agitation.

Formula B-5 illustrates the use of ARLASOLVE 200 Liquid/Gel to solubilize the fragrance in a foaming bath oil. The ratio of surfactant to perfume is dependent on the type of fragrance which is used.

Formula B-5
    BUBBLE BATH & BATH OIL   %, Weight
A   Fragrance   4.4
    ARLASOLVE 200 Liquid/Gel   q.s.
    Sodium lauryl sulfoacetate 70% active   10.0
B   Water   q.s. to 98.8
C   Lauramide DEA   1.0
    Preservative   0.2
        100.0

Preparation:

Add (B) to (A) with good agitation. Add (C) with stirring, with slight heating to facilitate solution when necessary. Adjust the final product to a pH of less than 7.0 with an acid such as citric. Filter if necessary.